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Electrochemical Cell Multiple Choice Test

Electrochemical Cell Multiple Choice Test 

Multiple Choice Questions for Electrochemical Cell



____                 1.  Oxidation is
a.       a gain of electrons.                        c.  a decrease in oxidation number
b.      an increase in oxidation number.  d.  removal of oxygen.
             2.  The oxidation number of sodium in a compound is
a.       0                                                    c.  +1
b.      +2                                                  d.  -1
             3.  Which of the following is an oxidation?
a.       Fe+3  +  e-  à   Fe+2                       c.  Fe  à  Fe+2  +  2e-
b.      Fe+3   +  3e-  à  Fe                        d.  Cl  +  e-   à  Cl-
             4.  Which of the following would be the best reducing agent?
a.         Cl2                                                 c.  O-2
b.      F-                                                    d.  Na+
             5.  What is the oxidation state of S in H2SO3?
a.       +2                                                  c.  0
b.      +4                                                  d.  +6
             6.  What is the oxidation number of Br in the BrO3- ion?
a.       -1                                                   c.  +5
b.      +1                                                  d.  +7
             7.  What kind of reaction is Cl2   à  Cl-  +  ClO2-( aside from unbalanced)?
a.       An oxidation                                 c.  an imposible reaction
b.      A reduction                                   d.  a disproportionation
             8.  In the reaction HNO2  +  I-   à  NO  + I2,  what atoms are being oxidized and reduced respectively?
a.       O, I                                                            c.  I, N
b.      I, O                                                            d.  N, I
             9.  What  is the next step in balancing the half reaction Cr2O7-2 à 2 Cr+3?
a.       add 7 H2O to the right                  c.  add 3.5 O2 to the left
b.      add 7 H2O to the left                    d.  add 8 electrons to the left
           10.  What is the next step in balancing the reaction SO3-2  +  H2O  à  SO4-2  +  2H+?
a.       add 3 H2O to the left                    c.  add 2 electrons to the left
b.      add 2 electrons to the right           d.  multiply through by 2
           11.  What is wrong with the REDOX reaction  2 Cl-  +  2Br-  à  Cl2  +  Br2?
a.       nothing is being oxidized              c.  chloride cannot be oxidized
b.      nothing is being reduced               d  bromide cannot be oxidized
           12.  The process by which electricity is used to bring about a chemical change is called
a.       corrosion.                                      c.  electrolysis.
b.      voltage.                                         d.  oxidation.
           13.  An electrochemical cell in which electrical energy drives nonspontaneous redox reactions.
a.       electrochemical cell                       c.  voltaic cell
b.      electrolytic cell                              d.  rechargeable battery
           14.  In a chemical cell composed of two half cells, ions are allowed to flow from one half-cell to the other by means of
a.       electrodes.                                     c.  a voltmeter.
b.      a wire.                                           d.  a salt bridge.
           15. The following reaction takes place in the electrolytic cell:
                        Zn(s)  +  Cu+2(aq)   à  Zn+2(aq)  +  Cu(s)
                  Which of the following statements is incorrect?
a.       Zinc is oxidized while copper ion is reduced.
b.      Zinc is the reductant while copper ion is the oxidant.
c.       Zinc loses two electrons while copper ion gains two electrons.
d.      Zinc undergoes reduction while copper ion undergoes oxidation.



           16.  Which of the following is not produced by the electrolysis of aqueous NaCl?
a.       Na                                                 c.  NaOH
b.      Cl2                                                 d.  H2
           17.  In voltaic cell reduction occurs at the
a.       anode.                                           c.  salt bridge.
b.      electrolyte.                                    d.  cathode.
           18.  In the reaction for a nickel-cadmium battery,
                        2Ni(OH)3   +   Cd    à  2Ni(OH)2   +   Cd(OH)2
                    Which species is oxidized during the discharge of the battery.
a.        Ni+3                                              c.  Cd
b.      Ni+2                                               d.  Cd+2
           19.  Which statement is incorrect about an electrolytic cell?
a.       The cell includes a battery.
b.      Reduction occurs at the cathode.
c.       The cell reaction is spontaneous.
d.      The electrodes may be inert (e.g. graphite) or may be involved in the cell reaction
           20.  Which statement is true for an electrochemical cell?
a.  Oxidation occurs at the anode only.
b.  Reduction occurs at the anode only.
c.  Oxidation occurs at both the anode and cathode.
                        d.  Reduction occurs at both the anode and cathode.
           21.  An iron ring is plated with zinc metal in the apparatus below.
Which of the following is true?
a. It is a voltaic cell and the reaction is spontaneous.
b. It is a voltaic cell and the reaction is not spontaneous.
c. It is an electrolytic cell and the reaction is spontaneous.
d. It is an electrolytic cell and the reaction is not spontaneous.
           22.  Which one of the following reactions is a redox reaction?
a.  Pb2+(aq) + 2Cl-(aq)  à  PbCl2(s)
b.  NaOH(aq) + HCl(aq)   à  NaCl(aq) + H2O(l)
c.  AgNO3(aq) + HCl(aq)  à  AgCl(s) + HNO3(aq)
d. 2Al(s) + 3Cl2(g) à  2AlCl3(s)
           23.  What is the term for the electrode where oxidation occurs?
a. anode                                               c. cathode
b. oxidizing agent                               d. reducing agent
           24.  Which of the following is true for an electrolytic cell?
a.  An electric current is produced by a chemical reaction.
b.  A nonspontaneous reaction is forced to occur.
c.  Electrons flow towards the anode.
d.  Electrons flow through the salt bridge.
           25.  The cell potential, E°, for an oxidation-reduction reaction was found to equal 1.10 V.  What can be said about this reaction?
a.  at equilibrium                                 c.  endothermic
b.  nonspontaneous                             d.  spontaneous
           26.  In an electrochemical cell, electrons travel in which direction?
a. from the anode to the cathode through the external circuit
b. from the anode to the cathode through the porous cup
c. from the cathode to the anode through the external circuit
d. from the cathode to the anode through the porous cup.
           27.  The diagram shows the electrolysis of molten KCl. What occurs when the switch is closed?
a.  Positive ions move toward the anode and gain electrons.
b.  Positive ions move toward the anode and lose electrons.
c.  Positive ions move toward the cathode and gain electrons.
d.  Positive ions move toward the cathode and lose electrons.




           28.  An electrochemical cell is set up with a copper electrode in contact with 1.0 mol/L CuSO4(aq) and a lead electrode in contact with 1.0 mol/L Pb(NO3)2(aq) . The standard reduction potentials are
                                                     
At 25° C, the standard cell potential for this galvanic cell in volts is a.
a.       0.13                                               c.  0.21
b.      0.34                                               d.  0.94
           29. Consider the following:
                                 
                                  
                                 
                                 
                                 
                        In an electrochemical cell, the combination of electrodes (and corresponding electrolytes) that would produce highest voltage is
a.                                                 c. 
b.                                                 d. 
           30.  An electric cell consists of a silver electrode in 1.0 mol/L solution of  (silver nitrate), a copper electrode in 1.0 mol/L solution of  (copper nitrate) and a salt bridge. The spontaneous cell reaction is
                       
                  When two electrodes are connected by a wire, which of the following does not take place?
a.       Electrons flow in the wire from the copper electrode to the silver electrode.
b.      The silver electrode increases in mass as the cell operates.
c.       There is a net movement of silver ions through the salt bridge from the silver half-cell to the copper half-cell.
d.      There is a net movement of copper ions through the salt bridge from the copper half-cell to the silver half cell
                       









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